Elements of Qualitative Chemical Analysis

W H William Henry Spencer

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Insol. In hydrate of ammonium.
Action of Water on Bismuthic Salts.
III.
Hydrate of Potassium.
4 HgCl+ 2 KHO yellows 2Hg 2 o insol. In excess of hydrate of potassium.
3 BiCl 3 + 3 H 2 white? BiCi 3 . Bi 2 o 3 insol. In tartaric acid (see Antimony, p. 24).
IV.
Iodide of Potassium.
HgCl + KI scarlet Hgl sol. In excess of iodide of potassium.
BiCl 3 + 3 KI brown (cystalline) BiI 3 insol. In excess of iodide of potassium.
V.
Chromate of Potassium.
sol. In acids.
yellow ............ Hg 2 . HgCr0 2 St...annous Chloride.
Metallic Iron.
2HgCl+SnCl white ppt Hg 2 Cl + SnCl grey deposits ...
= SuCl 2 + Hg 2 Cl .... Hg 2 Cl Hg VII.
Cyanide of Potassium.
Soluble + 3 KCr0 2 lemon-yellow Bi(CrO 2 ) 3 sol. In nitric acid and hydrate of ammonium, insol. In hydrate of potassium 8.
BiCl 3 + 3 KCy white BiCy 3 insol. In excess of cyanide of potassium.
\ a The white ppt. Is only produced by small quanti- ties of the reagent. If the experiment is carefully per- formed, the colour will become, according to the amount of reagent added, yellow, orange, brown, and finally black from formation of the black sulphide (Hg 2 S).

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