Energy Changes Involved in the Dilution of Zinc And Cadmium Amalgams

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Energy Changes Involved in the Dilution of Zinc And Cadmium Amalgams
Theodore William Richards
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008690 0. 008664 0. 00860 0. 20107 0. 00854 0. 00006 5-2 0. 008052 0. 008935 0. 00887 0. 29750 0. 00873 -0. 00014 5-6 0. 017615 0. 017597 0. 01747 0. 58857 0. 01727 -0. 00020 The second cell contained amalgams No. 2, No. 3 ; also No. 7 and No. 8, made by the dilution of No. 3 inside the cell to about one-half and one-quarter its original concentration.
Its temperature was 23. 03 C. = 296. 11, and the potential of the Helm- holtz cell was X = 0. 9929.
Potentials of Cadmium Amalgams. Second Serie
...s.
Pair ob- served.
IT observed as a fraction.
IT corrected fraction of X.
in international volts.
* IT calculated for t .
Difference v calc.
TTObS.
3-8 0. 017580 0. 017562 0. 017437 0. 59240 0. 017387 0. 00005 3-7 0. 008955 0. 008935 0. 008873 0. 30142 0. 008846 -0. 00003 2-3 0. 016915 0. 016906 0. 016785 0. 56850 0. 016685 -0. 00010 7-8 0. 008657 0. 008631 0. 008570 0. 29098 0. 008540 0. 00003 Calculated from 3-8 and 3-7, the value of DTT for 7-8 is 0. 00002, while from the direct reading the value is 0.


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