Excitation of Molecular Vibration By Collision

Cover Excitation of Molecular Vibration By Collision
Excitation of Molecular Vibration By Collision
Morris Salkoff
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Consequently the transi- tion probability depends critically on the potentials.
The difficulty i-iith the sensitivity of the inelastic cross section to the precise shape of the perturbation potential is not easily resolved. The per- turbation potential is not 'welL defined and can be obtained from an expansion of the unperturbed potential only if the molecules do not approach too closely. Inasmuch as a pertiirbation scheme is absolutely necessary for this many body problem, it is -55- clear tha
...t nore work must be done to find the correct correlation of the internal and external motions of the molecules.
VJe have also seen in Section 1 that the details of the unpertiirbed poten- tial for most molecular systems of interest are not known with arycertainty. Most of the work on the empirical fitting of a potential form to experimental data has concentrated on the region near V = 0. However^no work has yet been done that gives the repulsive wall of the potential acctirately. It is just this part of the potential that is needed for the calculation of an inelastic scattering cross section.


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