Exercises in Physical Chemistry

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Exercises in Physical Chemistry
Walther Adolf Roth
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1. When Glauber's salt is dissolved, a large amount of heat is absorbed, with common salt scarcely any. Accordingly, from the principle of least resistance* we expect the solubility of the former to increase greatly with rise of temperature, that of the latter but little ; such is actually the case. If, on the other hand, using a Dewar vessel, anhydrous Na 2 S0 4 is dissolved in water above 33, there will be a small * If a saturated solution of a completely dissociated binary electrolyte has at... the absolute temperature T, the concentration c, then dine g ~~dT~ ~ ~1RW> where q is the heat which the system evolves when one gram-molecule of substance is dissolved (for example see p. 59).
58 EXERCISES IN PHYSICAL CHEMISTRY evolution of heat ; this agrees with the fact that the solubility of anhydrous sodium sulphate decreases slowly with rise of temperature.
2. To determine the temperature change accurately it is necessary to use as solvent not pure water, but an almost saturated solution of the salt.


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