Gas Analysis

Cover Gas Analysis
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This method is naturally best applicable to the determination of hydrogen in the presence of nitrogen or of methane, or of both of these gases. A series of analyses of a mixture of hydrogen and nitrogen shows that the determination of hydrogen is accurate to within o.i cc. which falls well within the limits of experimental error when the sample is not greater than 100 cc.
and the analysis is made over water.
The high cost of the reagent would constitute a serious objec- tion to its employment i
...n technical practice were it not easily possible to regenerate it. This may be done^ as follows: The reagent is transferred from the gas pipette to a flask and the pipette is rinsed with water which is added to the liquid in the flask. Very dilute sulphuric acid is added drop by drop to the solution so long as a precipitate results. A large excess of sul- phuric add is to be avoided because it might cause the colloidal palladium to change to palladium sulphate through action of atmospheric oxygen.

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