General Principles of Organic Syntheses
General Principles of Organic Syntheses
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, with Liberation of Ammonia or Nitrogen. The amides of certain acids can be converted into esters with liberation of ammonia by the action of alco- hols in the presence of acids. Thus : NH 2 . CHO + C 2 H 5 . OH + HC1 = CHO. OC 2 By boiling urea with a large quantity of propyl alcohol, we have: 1 By the oxidation of a mixture of methyl and ethyl alcohols, there is ob- tained, not the mixed acetal, CH 3 . CH(OCH 3 )(OC2H 5 ), but a mixture of methyl and ethyl acetals.
CONDENSATIONS. 165 For the... preparation of ortho-esters (ortho-formic ester) y by the reaction of imide-ethers on alcohols, see page 153.
The diazo-compounds may be converted into esters under certain conditions. Thus, by decomposing the aromatic diazo- derivatives with acetic acid, the acetic esters of the phenols are obtained : CeH4 \N : N. S0 4 H The esters of diazo-acetic acid, on boiling with alcohol, give the esters of e thy 1-gly colic acid : CH
What to read after General Principles of Organic Syntheses?
You can find similar books in the "Read Also" column, or choose other free books by Petr Petrovich Alekskileev to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
, with Liberation of Ammonia or Nitrogen. The amides of certain acids can be converted into esters with liberation of ammonia by the action of alco- hols in the presence of acids. Thus : NH 2 . CHO + C 2 H 5 . OH + HC1 = CHO. OC 2 By boiling urea with a large quantity of propyl alcohol, we have: 1 By the oxidation of a mixture of methyl and ethyl alcohols, there is ob- tained, not the mixed acetal, CH 3 . CH(OCH 3 )(OC2H 5 ), but a mixture of methyl and ethyl acetals.
CONDENSATIONS. 165 For the... preparation of ortho-esters (ortho-formic ester) y by the reaction of imide-ethers on alcohols, see page 153.
The diazo-compounds may be converted into esters under certain conditions. Thus, by decomposing the aromatic diazo- derivatives with acetic acid, the acetic esters of the phenols are obtained : CeH4 \N : N. S0 4 H The esters of diazo-acetic acid, on boiling with alcohol, give the esters of e thy 1-gly colic acid : CH
What to read after General Principles of Organic Syntheses?
You can find similar books in the "Read Also" column, or choose other free books by Petr Petrovich Alekskileev to read onlineMoreLess
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