Hand book of Chemistry volume 10

Cover Hand book of Chemistry volume 10
Hand book of Chemistry volume 10
Leopold Gmelin
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. 100-00 Acetolcinate of Lead. When aqueous kiuic acid is boiled with a large excess of neutral acetate of lead, and the filtrate, evaporated to a syrup, is inked with alcohol, distinct crystals shoot out, containing acetic as well as kinic acid (Woskressensky). Ferric Kinate. Kinic acid protects ferric salts from precipitation by alkalis (Rose). Aqueous kinic acid is not coloured by ferric hydro- chlorate (Hesse). The pale yellow solution mixed with ferric hydro- chlorate assumes a deeper yell...ow colour, becoming dark-red on boiling, with formation of ferrous hydrochlorate (Wackenroder). _ The red- brown solution of ferric hydrate in aqueous kiuic acid, leaves when evaporated a semi-crystalline, very astringent mass, which does not become moist on exposure to the air, but is very soluble in water (Henry & Plisson). Si-acid (basic). Obtained accidentally on quickly evaporating a solu- tion containing kinates and ferric hydrochlorate. Microscopic laminee having the colour of chromic oxide, soluble in hydrochloric acid.

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