Hand book of Chemistry volume 4

Cover Hand book of Chemistry volume 4
Hand book of Chemistry volume 4
Leopold Gmelin
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Takes fire imme- diately in contact with crystallized chromic acid. Mixed with an equal volume of cold moderately strong nitric acid, it rises to the top, turns red, and afterwards green, and when gently heated gives off with violence nitrous vapours mixed with carbonic acid gas and an ethereal liquid smelling like butyric ether, while nitropropionic acid (ix. 430) remains behind. 5. When butyrone is distilled with pentachloride of phosphorus, phosphoric acid remains behind, and hydrochloric ac...id passes over, together with a cblorobutyrone, C U H 18 C1. [This product appears rather to be chlorobutylene, C 8 H 7 C1; q. V. ~\ Combinations. Butyrone is nearly insoluble in water, to which how- ever it imparts its odour. Mixes in all proportions with alcohol. Odmyl. ANDERSON (1847). Phil. Mag. J. 31, 161; also Ann. Pharm. 63, 370; also J. Pr. C/tem. 42, 1. 3 Ib. Of linseed or olive oil is gradually distilled for a whole day with a small quantity of sulphur, in a flask of 5 times the capacity of the liquid, over a fire which must be kept uniform and can be removed if the mixture threatens to froth over, a piece of sulphur being also added from time to time, so as to keep up a uniform effervescence; the distillate is received in a vessel surrounded with ice and fitted with a bent tube, to conduct the most volatile portion into a bottle containing VOL.

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