Hand book of Chemistry volume 6
Hand book of Chemistry volume 6
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Laurent (Methode de chimie, p. 108) regards it as the nitrile of benzilic acid = C- 8 NH 1] O 2 . Decompositions. 1. When fused, it yields the same products of decomposition as imabenzile. Distils apparently without decomposition, but the distillate dissolves very readily in ether and crystallises therefrom in needles by evaporation. 2. It is easily decomposed by hot nitric acid, with evolution of red vapours, and yields the same products as imabenzile. 3. It dissolves in gently heated oil of v...itriol, and the solution mixed with water deposits benzilam. 4. It is not decomposed by hydrochloric acid. It dissolves sparingly in alcohol and ether. Benzilam. C 28 NH 9 . LAURENT. (1845. ) Rev. Scient. 19, 443; J. Pr. Chem. 35, 464. Formation. 1. By the action of ammonia on benzile: C 28 H io 4 + NH 3 = C^NH 9 + 4HO. 2. By dissolving imabenzile or benzilim in oil of vitriol: C 2S NH"O 2 = C 28 NH 9 + 2HO. Preparation. 1. The thick crystals obtained in the preparation of benzilim' are purified by repeated crystallisation from cold ether-alcohol.
What to read after Hand book of Chemistry volume 6?
You can find similar books in the "Read Also" column, or choose other free books by Leopold Gmelin to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
Laurent (Methode de chimie, p. 108) regards it as the nitrile of benzilic acid = C- 8 NH 1] O 2 . Decompositions. 1. When fused, it yields the same products of decomposition as imabenzile. Distils apparently without decomposition, but the distillate dissolves very readily in ether and crystallises therefrom in needles by evaporation. 2. It is easily decomposed by hot nitric acid, with evolution of red vapours, and yields the same products as imabenzile. 3. It dissolves in gently heated oil of v...itriol, and the solution mixed with water deposits benzilam. 4. It is not decomposed by hydrochloric acid. It dissolves sparingly in alcohol and ether. Benzilam. C 28 NH 9 . LAURENT. (1845. ) Rev. Scient. 19, 443; J. Pr. Chem. 35, 464. Formation. 1. By the action of ammonia on benzile: C 28 H io 4 + NH 3 = C^NH 9 + 4HO. 2. By dissolving imabenzile or benzilim in oil of vitriol: C 2S NH"O 2 = C 28 NH 9 + 2HO. Preparation. 1. The thick crystals obtained in the preparation of benzilim' are purified by repeated crystallisation from cold ether-alcohol.
What to read after Hand book of Chemistry volume 6?
You can find similar books in the "Read Also" column, or choose other free books by Leopold Gmelin to read onlineMoreLess
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