Handbooks of Natural Philosophy And Astronomy

Cover Handbooks of Natural Philosophy And Astronomy
Handbooks of Natural Philosophy And Astronomy
Dionysius Lardner
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— Heat developed or absorbed in chemical combi- nation, — The development and absorption of heat, which accompany the action of chemical affinity, are, in the te:^t, ascribed either to a change of specific heat, or to an evolution or absorption of latent heat, consequent upon a change of state.
These causes are entirely inadequate, as will be evident from the following facts and considerations.
We must, in the first place, distinguish between the cases in which there is development of heat from
... those in which cold is produced.
Digitized by LjOOQ IC APPBNPIX. 171 Heat is always evolved wliere the action of chemioal affinity is defi- nite ; that is to say, where it results in the formation of a definite compound; — as water, e. g.y from t^e union of hydrogen and oxygen.
Cold, on the contrary, is produced only when the action of affinity is indefinite, as in the case of the solution of a solid in a liquid, where no definite compound is formed.
L The heat developed h^ the definite action of chemical ajjmitif cannot be explained either hy diminution of specific Jieaty or fty the eoohiMon of latent heat, consequent upon a chamge ofttate.


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