Heavy Metal Complexation With Naturally Occurring Organic Ligands in Wetland Ecosystems
Heavy Metal Complexation With Naturally Occurring Organic Ligands in Wetland Ecosystems
Tuschall, John Richard
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The lack of an observed correlation of manganese with F^S or DOC was expected since, according to equilibrium calculations (MINEQL), Mn + 2 was the predominant form of manganese under all experimental conditions; thus precipitation as MnS or complexation with DOC should not have occurred. 4. Zinc Zinc was added to the microcosms to an initial level of approxi- mately 100 yg/L, and after 120 h the aqueous concentrations of zinc ranged from 20 to 86 yg/L, corresponding to reductions of 18-84% (Ta...ble VI-6). The experimental F statistics (Table VI-7) indicate that pH and FUS were correlated with rates of zinc losses and that pH-HoS interaction was significant. These results are similar to those obtained for cadmium, which is not surprising since the two metals are similar chemically (Cotton and Wilkinson 1966). For exam- ple, both cadmium and zinc are associated with naturally occurring organic matter at approximately equal strength that typically is inter- mediate between the strong copper-organic complexes and the weaker 192 manganese-organic complexes (Irving and Williams 1948; Mantoura et al.
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