Historical Introduction to Chemistry Microform

Cover Historical Introduction to Chemistry Microform
Historical Introduction to Chemistry Microform
T Martin Thomas Martin Lowry
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The conclusions of XV THE MOLECULAR THEORY 353 Avogadro and Cannizzaro as to the number of atoms present in the molecules of various gases and vapours have been confirmed in a very striking way by independent physical methods. It is well known that the heat required to raise the temperature of a gas is greater when the gas is allowed to expand than when its volume is kept constant ; the ratio y of the two heat-capacities can be calculated to be 5/3=1-67 for an ideal or "perfect gas. " Experimen...t has shown that this value is rarely attained in the case of elements, and never in the case of compounds, and further that the value of y diminishes as the number of atoms in the molecule increases. Typical values are as follows : Substance. Ratio 7.
Hg, He 1-67 H 2, N 2, Oo, CO, HC1, HBr, HI 1-41 V C1 2, Br 2, I. , C1I I -29 to I -32 / C0 2, N 2 0, N0 2 i'3i It will be seen from the table that the value 1*4 is characteristic for the lighter diatomic gases and the figure i '3 for the heavier diatomic and the lighter triatomic gases, whether elementary or compound.


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