I a Separation of Arsenic Antimony And Vanadium From Tungsten Ii On the Com
I a Separation of Arsenic Antimony And Vanadium From Tungsten Ii On the Com
Orland Russell Sweeney
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1 The boiling was continued and a stream of carbon dioxide was passed to remove the excess of sulphur dioxide. When all the sulphur dioxide was expelled the solution was titrated, while still hot, with potassium permanga- nate. The permanganate was standardized, with pure vanadium pentoxide, which had been reduced in the same manner. The following results were obtained: Vanadio-tungstic acid. Percentage VaOs. Percentage WOs. 0. 2204 ... 65. 47 0. 3396 65. 31 0. 3227 16. 17 0. 3022 I5-92 65. 35 ...0. 3127 15. 90 0. 2460 15-95 65. 20 0. 2487 15. 95 65. 38 0. 1848 16. 09 65. 39 This latter method is so satisfactory that it is recom- mended in preference to the others. The temperature is easily regulated; the piece can be cooled quickly by re- moving the oven ; the danger of loss from creeping is slight ; and the volatile constituent is more quickly removed. 1 Repeated evaporation with hydrochloric acid will also effect this reduction. '7 CONCLUSIONS. 1. Methods are given for the separation of arsenic, antimony and vanadium from tungsten, which, it is be- lieved, are more satisfactory than those previously de- scribed.
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