I Colors of the Second Order Ii Mercuri Organic Derivatives

M S Morris Selig Kharasch

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12 thus obtained which was slightly soluble in water, imparting to the latter an intensely green color. The yield was very good.
Subs. , 0. 3618: 27. 40 cc. Dry N 2 at 24. 5 and 731 mm.
Subs. , 0. 4860: ZnO, 0. 0382.
Calc. For C3 2 H36N6Br 4 Cl2. ZnCl 2 : N, 8. 25; Zn, 6. 37. Found: N, 8. 36; Zn, 6. 31. The analysis readily shows that in this case also 2 molecules of the dye combine with one of zinc chloride.
The mercuric chloride double salt was obtained by solution of the zinc chloride double... salt in water at 40-50, and addition of mercuric chloride. The structure of the compound thus obtained is expressed by the follow- ing formula, V N ~V N i \ } I I ] . HgCl 2 .
/\Br' Br // \ // \N(CH 3 ) 2 / 2 1 Subs. , 0. 1373: HgS, 0. 0278. Calc. For C 3 2H 3 6Br 4 Cl2. HgCl 2 : Hg, 17. 17. Found: 17. 47.
Work is also under way on the isolation of the leuco-dibromo-Bind- schedler's Green, and the replacing in the latter of the 2 bromine atoms by mercury to give a compound of the following type, \N(CH 3 ) 2 which, when oxidized, would give a representative of a new class of or- ganic mercury derivatives.

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