I the Detection And Determination of Minute Quantities of Glycerine Ii the Vo
I the Detection And Determination of Minute Quantities of Glycerine Ii the Vo
Felton Samuel Dengler
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8 3. 651 3. 122 2. 659 2. 275 1. 376 1. 0 4. 12. " 3. 468 2. 881 2. 379 1. 756 A stud}' of the table shows that as the temperature is raised, the contraction, or the difference between the sum of the volumes of the solute and solvent on the one side, and the ob- served volume of the solution on the other side, diminishes. This decrease is not directly proportional to the rise in tempera- ture, but is greater between 15 and 20 degrees than it is be- luccn 20 and 25 or 25 and 30 degrees. At each ...temperature, the contraction is proportional to the concentration, as is also the decrease in contraction. Sufficient data is not at hand to pass final judgment on these facts, but it appears that as the temperature is raised, the observed volumes approaches that of the sum of the volumes of the solvent and solute. Whether or not they ever become equal remains for future investi cations to show. The two most concentrated so- 26 hitions were found to have lost in rotation while they were in the bath, but lack of time prevented repetition of the ex- periments.
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