Industrial And Manufacturing Chemistry: a Practical Treatise, volume 1

Cover Industrial And Manufacturing Chemistry: a Practical Treatise, volume 1
Industrial And Manufacturing Chemistry: a Practical Treatise, volume 1
Geoffrey Martin
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If the temperature is kept too high the sodium bicarbonate is of very coarse grain, and although well suited for the Thelen paos, it may not filter so well nor be so easily washed as material of a finer grain. At the same time the yield is, of course, considerably decreased, not only owing to the greater solubility of the salt at the higher temperature, but also owing to the increased partial pressure of the carbon dioxide in solution, and the consequent decreased efficiency with which the carb...on dioxide is absorbed. It must be remembered that only so long as the partial pressure of the carbon dioxide in the gas exceeds the partial pressure of the carbon dioxide in the liquor can absorption proceed.
Should the temperature of the liquor be brought too low, the resulting sodium bicarbonate is of a pasty consistency. It is almost impossible to filter or wash the material, and on calcining in the Thelen pans it is discharged in the form of small balls, the outside of which is the normal carbonate, whilst the interior is a core of the bicarbonate of sodium.


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