Inorganic Chemical Preparations

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(7) 12, 50.
Mix 75 grammes potassium fluorsilicate, 100 grammes granulated zinc, and 20 grammes sodium in small pieces. Throw the mixture into a red-hot crucible, and cover immediately. Unless the contents of SILICOCHLOROFORM 43 the crucible become liquid at once, heat to fusion and stir with a pipe-stem for a minute or two. Cool slowly, separate the lump of zinc, wash it carefully, and treat with com- mercial hydrochloric acid. Wash the resi- due, heat with concentrated nitric acid for a few m
...inutes, wash thoroughly, heat with hydrofluoric acid, wash and dry.
SILICOCHLOROFORM Friedel & Ladenburg, A. 143, 118. Gattermann, B. 22, 186, 190. Gattermann & Weinlig, B. 27, 1943. Vigouroux, A. Ch. P. (7) 12, 31.
Dry 25 grammes magnesium in the air- bath at 150, and while still warm (60 to 70) mix with 40 grammes warm sand pre- viously heated to redness, and then placed in a desiccator. Put the mixture into a small, flat, iron dish (sand-bath), pour upon it a 44 INORGANIC CHEMICAL PREPARATIONS coating of dry magnesium oxide, and cover with an iron plate or asbestos board.


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