Inorganic Chemistry
Inorganic Chemistry
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689 in solution. It is extremely unstable, and decomposes spontaneously when the solution is exposed to the light or is heated. When dry potassium permanganate is added to concentrated sulphuric acid, oily drops sepa- rate and collect upon the bottom of the vessel. These are manganese heptoxide, Mn 2 O 7, which is formed thus : 2KMnO 4 + H 2 SO 4 = K 2 SO 4 + Mn 2 O 7 + H 2 O.
The compound bears to permanganic acid the relation of an anhydride : 2HMnO 4 = Mn 2 O 7 + H, O.
It is extremely unstab...le, giving off oxygen with great ease, and therefore acting as a powerful oxidizing agent. As regards the constitution of the manganates and permanganates, they are respectively regarded as anal- ogous to the sulphates and perchlorates. Accord- ingly manganic acid is represented by the formula O HO-Mn-OH or MnO 2 (OH) 2, while permanganic acid is 6 o represented by the formula O=Mn-OH or MnO 3 (OH).
b Reactions which are of Special Value in Chemical Analysis. The conduct of manganous salts towards soluble hydroxides and towards soluble carbonates has been described.
What to read after Inorganic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Ira Remsen to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
689 in solution. It is extremely unstable, and decomposes spontaneously when the solution is exposed to the light or is heated. When dry potassium permanganate is added to concentrated sulphuric acid, oily drops sepa- rate and collect upon the bottom of the vessel. These are manganese heptoxide, Mn 2 O 7, which is formed thus : 2KMnO 4 + H 2 SO 4 = K 2 SO 4 + Mn 2 O 7 + H 2 O.
The compound bears to permanganic acid the relation of an anhydride : 2HMnO 4 = Mn 2 O 7 + H, O.
It is extremely unstab...le, giving off oxygen with great ease, and therefore acting as a powerful oxidizing agent. As regards the constitution of the manganates and permanganates, they are respectively regarded as anal- ogous to the sulphates and perchlorates. Accord- ingly manganic acid is represented by the formula O HO-Mn-OH or MnO 2 (OH) 2, while permanganic acid is 6 o represented by the formula O=Mn-OH or MnO 3 (OH).
b Reactions which are of Special Value in Chemical Analysis. The conduct of manganous salts towards soluble hydroxides and towards soluble carbonates has been described.
What to read after Inorganic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Ira Remsen to read onlineMoreLess
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