Intermolecular Rearrangement And Equilibrium of the Normal And Iso Propyl Bromid
Intermolecular Rearrangement And Equilibrium of the Normal And Iso Propyl Bromid
Helen Frances Goldstein Rafsky
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6 grams (f- propyl bromide) Fraction II 61 . 8 to 68. 0 2. 7 grams Fraction III 68 . To 70 . 7 3. 4 grams Fraction IV 70 . 7 to 71 . 5 4 . 45 grams (w-propyl bromide) Residue 1. 3 grams Total 13. 45 (b) IN TUBES AT ATMOSPHERIC PRESSURE UNDER VARYING CONDITIONS. In these experiments the apparatus employed by Brunei 21 was used. The gases entered separately coming to temperature, mixing, and passing on through the tubes together. They were then cooled by passing through a spiral condenser sur- ro...unded by an ice and salt freezing mixture. This experiment was tried at various temperatures and with gases of varying degrees of moisture and purity. The tube of the spiral con- denser was moistened with each, in turn, of the propyl bromides. However, under none of the conditions tried did the union take place to such an extent that anything could be collected. 21 /. Amer. Chem. Soc. , 39, 1997 (1917). 20 REACTION OF PROPYLENE AND AQUEOUS HYDRO- GEN BROMIDE (a) GASEOUS PROPYLENE AT ATMOSPHERIC PRESSURE.
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