Introduction to Physical Chemistry

Cover Introduction to Physical Chemistry
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Traube at 15. Kopp at b. P. C 9'9 ll'O H (in tirst hydroxyl group) (in subsequent hydroxyls) (in CO group) (attached to different C's) S (not attached to 0) Molecular co-volume .
3-1 5-5 2'3 7'8 0-4 7'8 5-5 12-2 5-5 7-8 15'5 22-6 25-9 It is apparent that there is little parallelism between the two sets of numbers, and that a knowledge of the constitution is even more necessary for Traube's treatment than for Kopp's.
From Kopp's equation for the molecular volume it is impossible to calculate a m
...olecular weight, since all the terms depend on the values for atoms only. It is possible to make the calculation from Traube's equation, because here, in addition to the atomic values, we have a 216 INTRODUCTION TO PHYSICAL CHEMISTEY CHAP.
term the co-volume which depends, not on the atoms, but on the molecule, having the constant value of 25 '9 cc. For each molecular quantity in grams.
Traube's mode of calculation may best be shown by means of a concrete example. A liquid is known to have the empirical formula C 8 H 14 3 =158, and it is also known that all the oxygen is combined with carbon only.


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