Introduction to the Study of Inorganic Chemistry: With Questions for Examination
Introduction to the Study of Inorganic Chemistry: With Questions for Examination
William Allen Miller , Wi Allen Miller
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CI; Atomic Wt 35*5 ; MoL Wt. 71 : Atomic Vol. n> ^P' ^^' 2-435; J^el. Wt. 35-5; Mol. Vol m (CU). Common table salt, or sodic chloride (NaCl), is the most abundant compound of chlorine. It is from this substance almost exclusively that chlorine is obtained; it is never found uncombined in nature. Exp. 115. — Mix 32 grams of finely powdered manganese di- oxide with an equal weight of common salt. Introduce them into a flask provided with a cork and bent . tube, and pour upon the mixture 84 c. c. ...of oil of vitriol previously diluted with 60 c. c. of water and allowed to cooL On heating the mixture gently, chlorine comes off" as a dense greenish-yellow suffocating gas, and may be collected in dry bottles by downward displace- ment* The chemical reactions may be thus shown : Manganese Sodic Sulphuric Manganese Hydric Sodic \a^.^, rki^— Diwdde Chloride Add Sulphate Sulphate ^*'^ Chlonne MnO, + 2NaCl + sHaSO^ - MnSO^ +2NaHS04 + 2H,0 + CI, Owing to the yellow colour of the gas, it can easily be seen when the bottle is full.
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