Ion Activity in Homogeneous Catalysis

Cover Ion Activity in Homogeneous Catalysis
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50 0. 01 0. 03 0. 05 0. 07 0. 10 0. 15 0. 20 0. 30 C 2 0. 00952 0. 02857 0. 04759 0. 06666 0. 09510 0. 1425 0. 1900 0. 2840 0. 4726 0. 6604 0. 9354 0. 1391 0. 00987 0. 02961 0. 0493 0. 0690 0. 0985 0. 1477 0. 1966 0. 2944 TABLE III 0. 470 N.
Ester (fc'FeHO 6 (*i'F e )-10 Ci 6. 11 611 18. 30 610 30. 00 600 41. 79 597 60. 15 601 91. 10 607 122. 2 611 185. 5 618 312. 4 625 45t). 0 643 640. 0 640 1006.
671 0. 100 N . Ester 6. 37 637 18. 96 632 31. 74 634 44. 44 635 63. 56 636 95. 54 637 129. 0 645
...197. 2 657 c, 642 641 630 627 632 639 643 653 661 681 684 723 645 640 644 644 645 647 656 670 Lapworth (Trans. Chem. Soc. , 99, 1427 [1911]) found that in the presence of large quantities of hydrochloric acid the equilibrium con- stant was somewhat greater than 4. With methyl acetate, at a con- centration of 1. 15 to 1. 74 normal, Griffith and Lewis (Jour. Chem. Soc. 109, 67 [1916]) obtained for K, in the presence of N/2 hydro- chloric acid, 4 . 30, 4 . 52, 4 . 66, and 4 . 80. Since no definite information regarding the value of K for the hydrolysis of ethyl acetate in the presence of hydrochloric acid of concentrations here employed could be obtained, the equilibrium constant was determined at each acid concentration.

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