Laboratory Exercises in Physical Chemistry
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Suppose that we have the system, Ag | 0. 001 -nAgNOa | n-KN0 3 | n-KN0 3 | Agl | Ag. The electromotive force of this combination is measured with due precautions and is found to be 0. 22 volt. In a 0. 001 n silver nitrate solution, dissociation is so nearly complete that we will commit no serious error in assuming the concentration of the silver ions to be 0. 001. From the formula we then have Iog 10 c' = 0. 058 log c-0. 22, or Iog 10 c' = 0. 058 logio 0. 001 - 0. 22. Solving, we find that c' =... 1. 6 X 10 - 8 or 1000 cc. Of a satu- rated solution of Agl contains 1. 6XlO~ 8 gram-molecules of Agl or 0. 0000035 gr. Agl. The corresponding value obtained by the conductivity method is 1. 5XlO~ 8 . Gas Cells. In the several cells which have been described in the preceding paragraphs, soluble reversible electrodes have been employed, the solution or deposition of the metal ions being the chief cause of the resulting electromotive force. If the soluble electrodes be replaced by platinum or some ELECTROMOTIVE FORCE.
What to read after Laboratory Exercises in Physical Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Frederick Hutton Getman to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
Suppose that we have the system, Ag | 0. 001 -nAgNOa | n-KN0 3 | n-KN0 3 | Agl | Ag. The electromotive force of this combination is measured with due precautions and is found to be 0. 22 volt. In a 0. 001 n silver nitrate solution, dissociation is so nearly complete that we will commit no serious error in assuming the concentration of the silver ions to be 0. 001. From the formula we then have Iog 10 c' = 0. 058 log c-0. 22, or Iog 10 c' = 0. 058 logio 0. 001 - 0. 22. Solving, we find that c' =... 1. 6 X 10 - 8 or 1000 cc. Of a satu- rated solution of Agl contains 1. 6XlO~ 8 gram-molecules of Agl or 0. 0000035 gr. Agl. The corresponding value obtained by the conductivity method is 1. 5XlO~ 8 . Gas Cells. In the several cells which have been described in the preceding paragraphs, soluble reversible electrodes have been employed, the solution or deposition of the metal ions being the chief cause of the resulting electromotive force. If the soluble electrodes be replaced by platinum or some ELECTROMOTIVE FORCE.
What to read after Laboratory Exercises in Physical Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Frederick Hutton Getman to read onlineMoreLess
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