Laboratory Outlines in Physical Chemistry
Laboratory Outlines in Physical Chemistry
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From these results determine the order of the reaction.
45 EXPERIMENTAL GROUP XII THE STUDY OF A REACTION The experiments which comprise this group constitute a detailed study of the reaction between oxalic acid, potassium permanganate and sulphuric acid, in aqueous solution: 5 (COOH) 2 + 2 KMn0 4 + 3 H 2 SO 4 = 2 MnSO 4 + K 2 SO 4 + 10 CO 2 + 8 H 2 O The reaction is familiar to every chemist because of the important part it plays in volumetric analysis.
Reference. Harcourt and Esson: Jour. Che...m. Soc. , 20, 460 (1867).
Discussion.
The reaction as written above is really the result of a series of simpler reactions. The reaction will be studied by means of velocity determinations made by ascertaining how much permanganate is used up under definite experimental conditions, and by systematically varying these conditions.
The important factors constituting the experimental conditions are the following: (1) Amount of KMnO 4 .
(2) Amount of oxalic acid.
(3) Amount of H 2 SO 4 .
(4) Amount of MnSO 4 .
What to read after Laboratory Outlines in Physical Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Thomas Roland Briggs to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
From these results determine the order of the reaction.
45 EXPERIMENTAL GROUP XII THE STUDY OF A REACTION The experiments which comprise this group constitute a detailed study of the reaction between oxalic acid, potassium permanganate and sulphuric acid, in aqueous solution: 5 (COOH) 2 + 2 KMn0 4 + 3 H 2 SO 4 = 2 MnSO 4 + K 2 SO 4 + 10 CO 2 + 8 H 2 O The reaction is familiar to every chemist because of the important part it plays in volumetric analysis.
Reference. Harcourt and Esson: Jour. Che...m. Soc. , 20, 460 (1867).
Discussion.
The reaction as written above is really the result of a series of simpler reactions. The reaction will be studied by means of velocity determinations made by ascertaining how much permanganate is used up under definite experimental conditions, and by systematically varying these conditions.
The important factors constituting the experimental conditions are the following: (1) Amount of KMnO 4 .
(2) Amount of oxalic acid.
(3) Amount of H 2 SO 4 .
(4) Amount of MnSO 4 .
What to read after Laboratory Outlines in Physical Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Thomas Roland Briggs to read onlineMoreLess
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