Laser-Excited Atomic Fluorescence in a Graphite Furnace
Laser-Excited Atomic Fluorescence in a Graphite Furnace
Goforth, Douglas Edmon
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The argon was turned off and the enclosure was pumped down to 25 torr. The sample was then atomized as before. The SRM samples were determined in the Ar atmosphere. For 58 these samples, a charring step was included with temperatures of 500 C for Mn and 600°C for Cu. Benefits of Computer System The major advantage of using the computer for dal^ reduction was that real time outputs were obtained. The data reduction routines allowed smoothing and background subtraction before measuring the integr...als of the peaks. L'vov (44) emphasized the importance of correlating the integrated absorbance reading (rather than peak absorbance) with concentration. A matrix can cause the peak to become shorter and broader, causing erroneous measurements for the peak height method but leaving the integral the same. Also, refractory- elements, such as Mo and V, tend to have severe tailing of the peak. An improved signal would result by using the integral method. Figure 3-2 shows a printout of one of the peaks for In in an Ar atmosphere.
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