Lecture Demonstrations in Physical Chemistry

Cover Lecture Demonstrations in Physical Chemistry
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P. 68.
CATALYSIS 65 sis of hydrogen peroxide by chromic acid, studied by Spitalsky. 1 The reaction is performed by carefully heating in a test-tube at 4O-5OC. 20 cc. Of a 20 per cent, solution of hydrogen peroxide (Merck's solution), to which has been added 5 cc. Of a N/ioo solution of chromic acid. The reaction starts slowly, the solution becoming blue ; after about 10 minutes a violent reaction takes place, the color of the solution changing into red-violet (induc- tion period). Finally the r
...eaction slackens and comes to a stop, and the original color of the chromic acid is re- stored.
TYPE 10.
70. The part played by so-called "germs" in catalysis is illustrated by an experiment, due to Luther, 2 and de- scribed by him as follows : Some word is written, with an alum crystal, on a clean glass plate. Invisible minute crystals remains, where the crystal has been passed. On pouring a super- saturated alum solution over the glass, crystallization starts at the "germs" and the word becomes visible.


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