Lessons in Elementary Chemistry

Cover Lessons in Elementary Chemistry
Lessons in Elementary Chemistry
Roscoe, Henry E. (Henry Enfield), 1833-1915
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On examination we find that only one such compound of silver and acetic acid exists ; and we find by experiment that 100 parts of silver acetate contain 64*68 parts by weight of silver ; hence, the molecular weight 01 the car- bon, hydrogen, and oxygen, united with silver (Ag = 108), is 35 3^ X^Q ^ 58-98. In this silver acetate, however, 64*00 one atom of hydrogen of the glacial icid was replaced by one of silver, so that the molecular weight of the glacial acetic acid is found to be r8-98-i-i
...=59*9^ or its formula is: 2 C = 24 4H= 4 20 = 32 60 The slight difference observed between the found (59*98) and the Calculated (60), molecular weight arises from 252 ELEMENTARY CHEMISTRY. [LESSON unavoidable errors of experiment; the more analyses of the substance are made, the nearer will the mean result approach the calculated numbers.
In a similar manner the molecular weights of organic bases are determined by ascertaining the weight of the substance which unites with a known weight of hydro- chloric acid to form a salt In the case of certain organic acids and bases, two or more compounds containing different proportions of silver (or other metal) and hydro- chloric (or other acid) are known, and it becomes a matter for consideration which of these is to be taken as con- taining one molecule of the organic compound to one atom of metal or acid ; the choice in these cases is determined by the general properties of all the conipounds, which never fail to point out the true character of the substance.


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