Lessons in Organic Chemistry

Cover Lessons in Organic Chemistry
Lessons in Organic Chemistry
George Sherbrooke Turpin
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Acetic acid treated with chlorine yields a derivative trichlor- acetic acid of the formula C. , C1 3 O . OH, in which the hydroxyl group is still present, and the other three hydrogens are re- placed by chlorine. Now trichloracetic acid readily yields chloroform when boiled with water : C, C1 3 O. OH = CHC1 3 + C0 2, Trichloracetic acid. Chloroform.
showing that all three Cl atoms, and therefore the three hydrogen atoms, whose places they occupy, are connected to the same carbon. Hence acetic a
...cid contains the groups CH 3 and OH, and the only formula in agreement with these experimental results is CH 3 . COOH.
General Methods of Preparation. (i) The first method is one which also furnishes valuable evidence in favour of the formula C, ; H 2w+1 . CO 2 H for the series, inasmuch as we start in each case from a substance, C ;, H

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