Mechanisms And Kinetics of Binary Alkali Silicate Glass Corrosion
Mechanisms And Kinetics of Binary Alkali Silicate Glass Corrosion
Ethridge, Edwin Clark
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The main objective of this chapter is to determine which mechanism is val id. The author believes that the Sykes' method 115 of preparing glass grains without agglomerates and fine particles is the best in the literature, however, it involves washing the glass grains with ether. Since this ether treatment might affect the glass corrosion kinetics another objective is to determine if an ether treatment alters the glass corrosion kinetics. Results and D iscussion The concentration of Li + that le...ached into the solution for each grain size range of 33L is shown in Fig. 10. As would be expected, one gram of the smaller grains leach more Li into the 50 ml of solu- tion than the larger grains. Nearly straight lines for the plots of log [Li + ] vs. log time are observed. The reaction rate exponents, 10 1 .JO 6 io"h 1 33L i 50°C Powders -100+200 -45+60 v^ V^ £) - A /* rv
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