Methods of Gas Analysis

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7 per cent of coal substance. If we assume that the coal sub- stance of a first-class brown coal contains 5. 8 per cent of hydrogen, then the air-dried coal contained rr rr r o - = 4. 45 per cent of hydrogen, from which, 100 in the combustion, would result 4. 45 x 9 = 40. 05 per cent water. 19. 5 per cent of hygroscopic water is, however, already present in the coal, therefore the combustion gases will contain 40. 05 + 19. 5 = 59. 5 per cent of water, which has 6 x 59. 5 = 357 calories of laten...t heat of evaporation. The air-dried coal therefore has an available heating power of 5818 357 = 5461 calories. Since, however, the original coal contained 7 per cent of "mine moisture, " the available heating power of the residual 93 per cent 2r 434 GAS ANALYSIS PART in of air-dried coal 5461 * 93 = 5078. 7 calories. To ascertain the available heating power of the coal containing "mine moisture, " the latent heat of evaporation of this " mine moisture, " 7 x 6 = 42 calories, must be subtracted from the result just obtained.

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