Modern Chemistry

Cover Modern Chemistry
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On adding more soda, the solution becomes alkaline, indicating the presence of free OH ions ; and it is only on concentration that these OH ions combine with the few H ions of the ionised Na 9 |=HPO 4, forming non-ionised water, and " tri-basic " PHOSPHATES 129 sodium phosphate, Na 3 PO 4, is left as a residue. Similar remarks apply to the ortho-arsenates. The ortho- vanadates are hydrolysed by water into pyro- and meta- vanadates.
The chief orthophosphates are: Na 2 HPO 4 . I2H 2 O, obtained b
...y neutralising phosphoric acid with sodium car- bonate ; HNa(NH 4 )PO 4 . 4H 2 O, named " microcosmic salt"; the human organism used to be known as the " microcosm, " and this salt crystallises out of concentrated urine; Ca 3 (PO 4 ) 2, prepared by precipitation, and found native , Ca PO 4 =Ca as phosphorite ; F Ca PO 4

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