Modern Electrical Theory Supplementary Chapters volume 15
Modern Electrical Theory Supplementary Chapters volume 15
Norman Robert Campbell
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: ~ (ra + a + av) 2 But usually for brevity we shall assume that (8) is quite accurate. A set of terms represented by (8), with varying m but constant a, is called a series of terms. (A series of terms must be distinguished from a series of lines, although the two are always closely connected. ) Every spectrum of which the terms are given by (8), and not by (7), has several such series of terms, characterised by different values of the constant a. In a typical spectrum these series are divided ...into four groups, which are conventionally distinguished by substituting for a the letters s, p, d, b. Thus the four groups are v s = (m, s), v p = (m, p), v d = (m, d), v b = (m, 6). This distinction is not arbitrary, for the four groups of series are distinguished by the lowest value of m which occurs in any term of them. Thus in (ra, s) m may have any value from 1 upwards; in (m, p) it may have any value from 2 upwards ; in (ra, d) any value from 3; in (ra, 6) any value from 4 1 . The normal state of the atom always corresponds to (1, s).
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