New Results in Electro Analysis

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New Results in Electro Analysis
Thomas Potter Mccutcheon
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It had a greenish, fluorescent appearance by reflected light. The solution was filtered without losing any of its properties. Addition of common salt produced a brownish red precipitate, which differed in appearance both from the hydrated dioxide of cerium, produced by conduct- ing chlorine into an alkaline cerous salt and from the hydrated trioxide, produced by the action of ammonia and 13 hydrogen peroxide on a cerous salt. The precipitate did not dissolve readily in hydrochloric acid, but di...ssolved in concentrated sulphuric acid with a yellow color. In this latter respect it resembled the dioxide. The same precipitate formed on allowing the purple solution to stand several days or on continuing the electrolysis for about an hour. A pressure of 8 volts seemed to be most favorable for the formation of this compound. It appeared to be a derivative of cerium in a colloidal condition. A further study of this compound will be made immediately.
ELECTROLYSIS OF CALCIUM CHLORIDE A more careful study was next made of the behavior of calcium chloride in the cell.


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