Notes On Qualitative Analysis

Cover Notes On Qualitative Analysis
Notes On Qualitative Analysis
Louis Agassiz Test
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, AuCl 3 and PtCl 4 .
H 2 S0 4 (cone. ), warm : HC1 gas, which turns blue litmus paper red.
NOTE. The cone. H 2 SO 4 test can usually be applied either to the solid salt or to its sol.
WET TESTS. Diss. 'i gm. NaCl in 5 c. C. Of aq.
AgNO ;! : white curdy ppt. Of AgCl which darkens on exposure to light. Insol. In HNO i(, sol. In NH 4 OH, KCy, etc. Fuses to a horny mass.
H 2 S0 4 and Mn0 2, warm : Cl, which bleaches litmus paper.
K 2 Cr 2 07 (about 0*1 gm. In powder) and 2 c. C. Of H 2 SO 4, on wa
...rming with a dry chloride evolve red-brown vapours of chromyl chloride (CrO 2 Cl 2 ) which condense to a dark red liquid.
Hypochlorous Acid. HC10.
DRY TESTS. Hypochlorites when heated are converted into chlorides and chlorates. The CO 2 in the air decomposes them with evolution of chlorine, 35 36 CHLORIC ACID, PERCHLORIC ACID AND HYDROBROMIC ACID WET TESTS. Diss. ;i gm. NaCIO in 6 c. -c. Of cold aq. , or pass Cl into 6 c. C. Cold dil. NaOH sol.
Litmus, Indigo, etc. , are bleached by aqueous solutions of hypo- chlorites.


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