On the Rate of Formation of Carbon Monoxide in Gas Producers
On the Rate of Formation of Carbon Monoxide in Gas Producers
J K John Kay Clement
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055 c 2 = 0. 003104 C = 8. 604 In the determination of c l and c 2, Langen's values for the specific heats of CO and CO 2 and the value of Kunz for the specific heat of charcoal were employed. The value of R (in gram-calories per deg. ) is 1. 985. Hence taking the above constants and this value of R, (19) reduces to lnK = - + 1. 035 InT 0. 001564 T + 8. 604. (20) Table 9 gives values of K calculated from equation (20) along with values (marked Koi* ) obtained from observed values of x and T in ...tables 1-6. In the fourth column are the observed values of x, the amount of CO in equilibrium with CO 2 and charcoal at temperatures from 800 to 1100 ; and in the fifth columns the values of x corresponding to the values of K in the third column. 22 ILLINOIS ENGINEERING EXPERIMENT STATION The constants of equation (19) were calculated also by the method of least squares, from simultaneous values of Kois and T, but the agreement was less satisfactory than by the first method. TABLE 9 VALUES OF K AND OF X Temp.
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