On the Speed of the Liberation of Iodine in Mixed Solutions of Potassium Chlorat

Cover On the Speed of the Liberation of Iodine in Mixed Solutions of Potassium Chlorat
On the Speed of the Liberation of Iodine in Mixed Solutions of Potassium Chlorat
Herman Schlundt
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3 cc.
Water .. . 186. 7 cc.
400. 0 cc.
Cubic centimeters Duration of reac- tion in minutes.
Cubic centimeters of solution taken.
of n. Na, S f 8 used in each titration.
Per cent, of Iodine liberated.
20 20 15. 3 38. 3 50 20 24. 55 61. 4 100 20 (C S 2 ) 31. 7 79. 3 100 20 31. 8 79. 5 200 20 37. 15 92. 9 300 20 38. 85 97. 1 460 20 39. 55 98. 9 After 24 hours 20 cc. Of this mixture kept at the ordinary temperature of the laboratory required 0. 5 cc. Of twentieth normal sodium thiosulphate.
1 Curve
... D, Figure 3.
8CHLUNDT SPEED OF THE LIBERATION OF IODINE 19 SECTION C.
This section embraces a series of experiments in which excesses of both the hydrochloric acid and potassium iodide enter, the amount of potassium chlorate remaining constant. The results obtained have a direct bearing upon analytical methods as these are the conditions under which chlorates are estimated.
(1) Series in which botJi the H Cl and K I are doubled* the K Cl O 3 remaining constant and tenth normal, 1 Excess K Cl O 3 + 6 KI + 6 H Cl + 6 H Cl + 6 K I.


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