Organic Chemistry
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In our eReader you can find the full English version of the book. Read Organic Chemistry Online - link to read the book on full screen. Our eReader also allows you to upload and read Pdf, Txt, ePub and fb2 books. In the Mini eReder on the page below you can quickly view all pages of the book - Read Book Organic Chemistry
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It may be prepared synthetically by digesting ^-hydroxybenzaldehyde with alcohohc potash and methyl iodide, C6H^<^jjQ + CH3I = ^S^i^Q^Q + ^^ Anisaldehyde boils at 248°, and has a penetrating, aromatic odour; on reduction with sodium amalgam it yields anisyl alcohol, C6H4(OCH3)-CH2-OH (p. 417); oxidising agents convert it into anisic acid, CgH^(0CH3)-C00H (p. 452). Ketones. The ketones of the aromatic, like those of the fatty series, have the general formula E-CO-E', where E and E' re- present different or identical radicles, one of which must, of course, be aromatic. Acetopheuone, phenylmethyl ketone, or acetylbenzene, CgHg-CO-CHg, may be described as a typical aromatic ketone. It is formed on distilling a mixture of calcium benzoate and calcium acetate, a reaction which is exactly analogous to that which is made use of in obtaining mixed ketones of the fatty series, (CeH5-COO)2Ca + (CH3.COO)2Ca = 2C6H5.CO.CH3 + 2CaC03. It is most conveniently prepared by dropping acetyl chloride 424 AROMATIC ALCOHOLS, ALDEHYDES, (1 mol.) into Avell-qooled benzene (1 mol.) in presence of aluminium chloride, CgHe + CHg-COCl = CeHj-CO-CHg + HCL This method is of general use, as by employing other acid chlorides and other hydrocarbons, many other ketones may be prepared ; it is an extension of Friedel and Crafts' method of preparing hydrocarbons (p.
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To quickly assess the difficulty of the text, read a short excerpt:
It may be prepared synthetically by digesting ^-hydroxybenzaldehyde with alcohohc potash and methyl iodide, C6H^<^jjQ + CH3I = ^S^i^Q^Q + ^^ Anisaldehyde boils at 248°, and has a penetrating, aromatic odour; on reduction with sodium amalgam it yields anisyl alcohol, C6H4(OCH3)-CH2-OH (p. 417); oxidising agents convert it into anisic acid, CgH^(0CH3)-C00H (p. 452). Ketones. The ketones of the aromatic, like those of the fatty series, have the general formula E-CO-E', where E and E' re- present different or identical radicles, one of which must, of course, be aromatic. Acetopheuone, phenylmethyl ketone, or acetylbenzene, CgHg-CO-CHg, may be described as a typical aromatic ketone. It is formed on distilling a mixture of calcium benzoate and calcium acetate, a reaction which is exactly analogous to that which is made use of in obtaining mixed ketones of the fatty series, (CeH5-COO)2Ca + (CH3.COO)2Ca = 2C6H5.CO.CH3 + 2CaC03. It is most conveniently prepared by dropping acetyl chloride 424 AROMATIC ALCOHOLS, ALDEHYDES, (1 mol.) into Avell-qooled benzene (1 mol.) in presence of aluminium chloride, CgHe + CHg-COCl = CeHj-CO-CHg + HCL This method is of general use, as by employing other acid chlorides and other hydrocarbons, many other ketones may be prepared ; it is an extension of Friedel and Crafts' method of preparing hydrocarbons (p.
What to read after Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by William Henry Perrin to read online
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