Organic Chemistry Including Certin Portions of Physical Chemistry for Medical
Organic Chemistry Including Certin Portions of Physical Chemistry for Medical
Howard Davis Haskins
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C. Of acetone in dilute H 2 S04, * add KMn(>4 solution until a pink color remains on warming. Filter, make the filtrate strongly acid with 20% H 2 S0 4, and distill. Test the distillate for acetic acid (see p. 163). (3) Shake 5 c. C. Of acetone with 8 c. C. Of a saturated solution of sodium bisulphite; cool; crystals of the addition compound of acetone appear. Filter and wash. Save samples. Chloretone (chloroform acetone, trichlor-tertiary- /O H butyl-alcohol), CH 3 (Xj- CC1 3, is an addition X... CH 3 product of acetone. It is formed by the interaction of acetone and chloroform in the presence of an excess of KOH, It is a useful hypnotic. 192 ORGANIC CHEMISTRY Brometone, the corresponding bromine prepara- tion, produced from acetone and bromoform, is analogous to chloretone. As a remedy it is used instead of bromides. Ketone acids. Some acids contain both the car- bony! and carboxyl groups. Aceto-acetic acid, CH 3 -CO-CH 2 -COOH, typifies these, and is of importance, since it may occur in the urine (see p.
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