Organic Chemistry Including Certin Portions of Physical Chemistry for Medical

Cover Organic Chemistry Including Certin Portions of Physical Chemistry for Medical
Organic Chemistry Including Certin Portions of Physical Chemistry for Medical
Howard Davis Haskins
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C. Of acetone in dilute H 2 S04, * add KMn(>4 solution until a pink color remains on warming. Filter, make the filtrate strongly acid with 20% H 2 S0 4, and distill. Test the distillate for acetic acid (see p. 163).
(3) Shake 5 c. C. Of acetone with 8 c. C. Of a saturated solution of sodium bisulphite; cool; crystals of the addition compound of acetone appear. Filter and wash. Save samples.
Chloretone (chloroform acetone, trichlor-tertiary- /O H butyl-alcohol), CH 3 (Xj- CC1 3, is an addition X
... CH 3 product of acetone. It is formed by the interaction of acetone and chloroform in the presence of an excess of KOH, It is a useful hypnotic.
192 ORGANIC CHEMISTRY Brometone, the corresponding bromine prepara- tion, produced from acetone and bromoform, is analogous to chloretone. As a remedy it is used instead of bromides.
Ketone acids. Some acids contain both the car- bony! and carboxyl groups. Aceto-acetic acid, CH 3 -CO-CH 2 -COOH, typifies these, and is of importance, since it may occur in the urine (see p.


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