Organic Chemistry Or Chemistry of the Carbon Compounds volume 1
Organic Chemistry Or Chemistry of the Carbon Compounds volume 1
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In our eReader you can find the full English version of the book. Read Organic Chemistry Or Chemistry of the Carbon Compounds volume 1 Online - link to read the book on full screen. Our eReader also allows you to upload and read Pdf, Txt, ePub and fb2 books. In the Mini eReder on the page below you can quickly view all pages of the book - Read Book Organic Chemistry Or Chemistry of the Carbon Compounds volume 1
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1904, I. 659 ; 1906, I. 912).
The aci-ether is readily hydrolyzed by dilute sulphuric acid into the j8-ketone acid ether.
NITROGEN DERIVATIVES OF -KETONIC ACIDS 419 fi-Dithioethyl Butyric Ester, CH 3 C(SC 2 H 6 ) 2 CH 2 CO 2 C 2 H 6, b. P. 37 138, is decom- posed by hydrolysis into mercaptan andfi-Thioethyl Crotonic Acid, CH a C(SC 2 H 6 ) : CHCO a H, m. P. 91 (B. 33, 2801 ; 34, 2634).
Esters of the aci-/?-Ketonic Acid Esters.
Acid chlorides and also halogen alkyls, acting on sodium acetoacetic... ester, produce mainly the C-acyl compounds (described later among the diketo-carboxylic esters). Some O-acyl ester is also formed, which can be obtained as a main product, by the action of acid chlorides on acetoacetic ester in the presence of pyridine. The O-acyl esters are insoluble in alkalis, whilst the C-acyl esters are soluble, thus providing an easy method of separation. When heated with alkalis (potassium carbonate, sodium acetoacetic ester, etc. ), the O-acyl esters are transformed into C-acyl esters.
What to read after Organic Chemistry Or Chemistry of the Carbon Compounds volume 1?
You can find similar books in the "Read Also" column, or choose other free books by Victor Von Richter to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
1904, I. 659 ; 1906, I. 912).
The aci-ether is readily hydrolyzed by dilute sulphuric acid into the j8-ketone acid ether.
NITROGEN DERIVATIVES OF -KETONIC ACIDS 419 fi-Dithioethyl Butyric Ester, CH 3 C(SC 2 H 6 ) 2 CH 2 CO 2 C 2 H 6, b. P. 37 138, is decom- posed by hydrolysis into mercaptan andfi-Thioethyl Crotonic Acid, CH a C(SC 2 H 6 ) : CHCO a H, m. P. 91 (B. 33, 2801 ; 34, 2634).
Esters of the aci-/?-Ketonic Acid Esters.
Acid chlorides and also halogen alkyls, acting on sodium acetoacetic... ester, produce mainly the C-acyl compounds (described later among the diketo-carboxylic esters). Some O-acyl ester is also formed, which can be obtained as a main product, by the action of acid chlorides on acetoacetic ester in the presence of pyridine. The O-acyl esters are insoluble in alkalis, whilst the C-acyl esters are soluble, thus providing an easy method of separation. When heated with alkalis (potassium carbonate, sodium acetoacetic ester, etc. ), the O-acyl esters are transformed into C-acyl esters.
What to read after Organic Chemistry Or Chemistry of the Carbon Compounds volume 1?
You can find similar books in the "Read Also" column, or choose other free books by Victor Von Richter to read onlineMoreLess
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