Organic Chemistry Or Chemistry of the Carbon Compounds volume 2

Cover Organic Chemistry Or Chemistry of the Carbon Compounds volume 2
Organic Chemistry Or Chemistry of the Carbon Compounds volume 2
Victor Von Richter
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On esters and ester acids from o- and p-sulpho-benzoic acid, see M. 23, 1093.
3, 5-Disulpho-benzoic acid is formed by heating benzoic acid with fuming sulphuric acid containing 70 per cent. SO 3 to 250 in a pressure tube (B. 35, 2305). 2, 4-Disulpho-benzoie acid, from 2, 4-toluol- disulphonic acid (B. 14, 1205).
Diphenyl-sulphone-o-monocarboxylic acid C 6 H 5 SO 2 [2]C 6 H 4 [i]COOH, m. P. 144, is formed by oxidation of phenyl-o-tolyl-sulphone and phenyl-thio-salicylic acid with KMnO 4, or by h
...eating the potassium salts of o-chloro-benzoic acid and benzol-sulphinic acid in aqueous or amyl-alcoholic solution, in the presence of copper. On heating with concentrated H 2 SO 4 the acid passes into benzo-phenone-sulphone C 6 H 4 C 6 H 4 (B. 38, 729 ; C. 1905, L 1394)- (d) MONOHYDRIC OXY-PHENYL-PARAFFIN ALCOHOLS AND THEIR OXIDATION PRODUCTS.
i. Monohydrie Oxy-phenyl-paraffin Alcohols, or Phenol Alcohols.
These alcohols contain, in addition to the alcoholic hydroxyl, other hydroxyl groups joined to the benzene nucleus, which impart to them MONOHYDRIC OXY-PHENYL-PARAFFIN ALCOHOLS 315 the character of phenols.


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