Organic Compounds of Mercury
Organic Compounds of Mercury
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P. 120 (121. 8, 12 125-6 13 ). It is best recrystallized from hot benzene or chloroform. (CHHg). The white crystals turn yellow in light. It is insoluble in water, easily soluble in chloroform, carbon disulfide, ben- zene, less soluble in ether and boiling alcohol. It is slightly volatile with steam. It sublimes on heating above its melting point. It can- not be distilled under ordinary pressure as it decomposes giving mer- cury, benzene, diphenyl, carbon, and other products. B. P. 10 . 5 204. ...Its density varies from 2. 29 to 2. 34.
A solution of mercury diphenyl in chloroform shows no absorption bands as it is remarkably transparent to all wave lengths. It absorbs light less than does mercuric iodide whereas benzene absorbs light more than hydrogen iodide. 14 It absorbs the longer wave lengths more than does benzene.
Mercury diphenyl is toxic. It has a very irritating effect on the eyes. 15 Reactions.
1. With halogens.
Dry chlorine gives a vigorous reaction forming phenyl mercuric chloride, phenyl chloride, and some mercuric chloride.
What to read after Organic Compounds of Mercury?
You can find similar books in the "Read Also" column, or choose other free books by Frank C Frank Clifford Whitmore to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
P. 120 (121. 8, 12 125-6 13 ). It is best recrystallized from hot benzene or chloroform. (CHHg). The white crystals turn yellow in light. It is insoluble in water, easily soluble in chloroform, carbon disulfide, ben- zene, less soluble in ether and boiling alcohol. It is slightly volatile with steam. It sublimes on heating above its melting point. It can- not be distilled under ordinary pressure as it decomposes giving mer- cury, benzene, diphenyl, carbon, and other products. B. P. 10 . 5 204. ...Its density varies from 2. 29 to 2. 34.
A solution of mercury diphenyl in chloroform shows no absorption bands as it is remarkably transparent to all wave lengths. It absorbs light less than does mercuric iodide whereas benzene absorbs light more than hydrogen iodide. 14 It absorbs the longer wave lengths more than does benzene.
Mercury diphenyl is toxic. It has a very irritating effect on the eyes. 15 Reactions.
1. With halogens.
Dry chlorine gives a vigorous reaction forming phenyl mercuric chloride, phenyl chloride, and some mercuric chloride.
What to read after Organic Compounds of Mercury?
You can find similar books in the "Read Also" column, or choose other free books by Frank C Frank Clifford Whitmore to read onlineMoreLess
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