Osmotic Pressure

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In this way the directly determined values may be checked, and one may also obtain, indirectly, values of the osmotic pressure with an accuracy esti- mated by Porter at about I part in 1 500.
The variation of osmotic pressure with the temperature has also been studied by W. F. Magie, " who has proposed the fol- lowing formula for the osmotic pressure : / = aO log 6 + (b - a) + e AQUEOUS SOLUTIONS OF CANE SUGAR 71 where a is a quantity determined by observations of the heat capacity of the solut
...ions, and b and e are constants of integration. On the assumption that a is independent of the temperature, e is connected with the heat of dilution, / by the formula / = - aO + e.
If p s represents the osmotic pressure of the solution at the temperature # Si one obtains p _p s _ 0-Os 7\ ~~ 7j~ "t~ # 1S /} ^ /)/} / U & U s UU S This formula was tested by means of the vapour pressure deter- minations of Emden 10 for solutions of sodium chloride, and was found to be in harmony with the experimental results.


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