Outlines of General Chemistry

Cover Outlines of General Chemistry
Outlines of General Chemistry
Wilhelm Ostwald
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We therefore move the carriage with d along the wire ab until we find the spot at which the telephone no longer speaks. As R : W = ad : db, the resistance W required is equal to R r, or the conductivity L = == = a . To calculate the equivalent or molar conductivity from the con- ductivity so obtained for the liquid in W, we must multiply the latter 'by the "capacity" of the resistance-cell, and also by the 1 The wire may be of platinum or of constantan or similar resistance wire ; it should hav...e as great a resistance as possible. A wire metres. CHAP. XV ELECTROLYTIC CONDUCTION 387 dilution, i. E. The number of litres in which a gram equivalent or a mol of the electrolyte is contained. The capacity is found by introducing into the cell a liquid of known conductivity and composition, and finding its resistance. If M is the molar con- ductivity of the liquid, and V its dilution, then we obtain the factor K for transforming the conductivity measured in the cell into molar conductivity from the equation V.

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