Outlines of Modern Chemistry Organic Based in Part Upon Riches Manuel De Chim
Outlines of Modern Chemistry Organic Based in Part Upon Riches Manuel De Chim
Charles Gilbert Wheeler
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It is a base which saturates two molecules of a monobasic acid. SULPHATES OF QUINIA. Two sulphates of quinia are known; that obtained by the process we have above 154 ORGANIC CHEMISTRY. described, is the neutral sulphate, though generally known as the basic sulphate. Its formula is This salt contains 74. 3 per cent, of quinia. It crystallizes in very delicate needles belonging to the clinorhombic system, and which effloresce in dry air. It dissolves in 30 parts of boiling and 740 parts of cold ...water; also in 60 parts of cold absolute alco- hol. It is very nearly insoluble in ether. Its solu- tions are extremely bitter. It becomes phosphorescent on being heated, and subsequently fuses. Heated in the air it burns, leaving a carbonaceous residue. On adding quinia to water acidulated with sulphuric acid, it rapidly dissolves and another sulphate, often called the acid sulphate, is formed, whose formula is It is on account of the difficult solubility of the pre- ceding salt, and the great solubility of this latter one, that we cautioned against the employment of an excess of sulphuric acid in the preparation of quinia.
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