Outlines of Physical Chemistry

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Cf. Also Philip, Trans. Chem. Soc. , 1907, 9L 7".
346 OUTLINES OF PHYSICAL CHEMISTRY temperature coefficient of the mechanical friction of water. This observation at once becomes intelligible if it is assumed that the ions are surrounded by water molecules, as the resist- ance to movement of the water-coated ions would then be the frictional resistance of water against water.
Many attempts have been made to determine the degree of hydration both in solutions of electrolytes and of non- electrol
...ytes, but the results are very uncertain. If each ion becomes associated with a number of water-molecules, the total number of solute particles will not be altered, and the osmotic pressure, lowering of freezing-point, etc. , will not be directly affected. If, however, it is assumed that only the un- bound part of the solvent can really act as solvent, the effect of association will be to diminish the "free " solvent, and there- fore the effective concentration of the solution the ratio of solute to free solvent will be increased, and the lowering of freezing-point will be greater than the calculated value.

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