Outlines of Physiological Chemistry
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As a rule when an OH group is attached to N the latter is pentatomic thus : N-N-H + ./^ H,0 = ^N^O-H H ^ CYCLIC COMPOUNDS. 85 N-N— I But one of the H atoms attached to NH, may exceptionally be oxidized without N becoming pentatomic.
Y -H + O = H-N-0— H Ammonia. Hydrozylamin.
The reason for calling this an amin is obvious, for if the C3 is replaced by — C s R we have one of the ordinary amins with which we are already familiar.
Hydroxylamin may unite with NH, with loss of water : J- -±2^K+Kr'^-^... = H^~NH, + H,0 Hydrozyl amin + Ammonia =» Hydrazin, NaH4.
When an N is attached to another N this is designated by — az — . Thus we have : Aso conu>oand. Diazo compound.
Hydrazin does not occur free but only in combination, mainly with organic compounds — open or closed chains : OHO-H+iiHN . NH, = /N — NH • NH, Phenol+bydradn. Phenyl hydrazin.
Reactions with Benzoyl Chloride and Phenylisocyanate.
It is much easier to isolate a substance, i. e., to get it in pure form free from impurities, if it is crystallizable rather than amorphous.
What to read after Outlines of Physiological Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Silas Palmer Beebe to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
As a rule when an OH group is attached to N the latter is pentatomic thus : N-N-H + ./^ H,0 = ^N^O-H H ^ CYCLIC COMPOUNDS. 85 N-N— I But one of the H atoms attached to NH, may exceptionally be oxidized without N becoming pentatomic.
Y -H + O = H-N-0— H Ammonia. Hydrozylamin.
The reason for calling this an amin is obvious, for if the C3 is replaced by — C s R we have one of the ordinary amins with which we are already familiar.
Hydroxylamin may unite with NH, with loss of water : J- -±2^K+Kr'^-^... = H^~NH, + H,0 Hydrozyl amin + Ammonia =» Hydrazin, NaH4.
When an N is attached to another N this is designated by — az — . Thus we have : Aso conu>oand. Diazo compound.
Hydrazin does not occur free but only in combination, mainly with organic compounds — open or closed chains : OHO-H+iiHN . NH, = /N — NH • NH, Phenol+bydradn. Phenyl hydrazin.
Reactions with Benzoyl Chloride and Phenylisocyanate.
It is much easier to isolate a substance, i. e., to get it in pure form free from impurities, if it is crystallizable rather than amorphous.
What to read after Outlines of Physiological Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Silas Palmer Beebe to read onlineMoreLess
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