Ozone

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Der Physik, " 2, 39, 321, 1890) and Well and Kopp (" Jahresber. Chem. , " 270, 1889, 322, 1890) observed the formation of ozone by passing oxygen over hot platinum, indicating the reversibility of the catalytic activity of the platinum.
In many cases the activity of these catalytic materials 136 OZONE can be attributed to the formation and subsequent decom- position of an unstable oxide or peroxide, e. G.
2Ag + 3 -> Ag 2 + O 2 - Ag.
Manchot ("Ber. , " 39, 1510, 1906; 40, 2891, 1907; and 42, 394
...8, 1908), as a result of a series of experiments, obtained some interesting results with silver as a catalytic agent. He noted that pure silver was relatively stable in the presence of ozone, it being necessary to warm the metal up to 24 C. Before decomposition of the ozone and formation of silver oxide occurred.
A trace of iron, usually obtained from the emery powder employed for cleaning the silver, serves as an excellent catalyst promoter, silver containing but a minute trace of iron reacts already at normal temperatures, and less than O'Ol per cent, of ozone can be detected by this means.


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