Perkin's Reaction

Cover Perkin's Reaction
Perkin's Reaction
Gibson Dyson
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— 12 — The following are the analytical numbers obtained : — I. 0*3861 grammes of salt gave on heating at I30°C.
0*04725 grammes of water, and on treatment with sulphuric acid 0*1047 grammes of barium sulphate.
Calculated on the dried salt. Found.
Ba=i8*i8 0/0 Ba= 18*140/0 The formula (Ci8Hi305),Ba+6HaO requires 12*510/0 of water. Found 1 2*2 0/0.
II. 0*31275 grammes of the salt gave 0*05675 grammes of water, and on treatment with sulphuric acid 0*0787 grammes of BaS04.
Calculated on dried salt
.... Found.
Ba= i8*i8 0/0 Ba= 18*34 Vo Calculated for (Ci8Hi305)aBa + 9HiO = 17-66 0/0 of water.
Found 18*14 °/o.
Silver Salt CisHuOfiAg.
On addition of silver nitrate to a solution of the barium salt, the silver salt was obtained as a white curdy precipi- tate, which on standing became crystalline. It is almost insoluble in water.
The analysis of the salt, dried over sulphuric acid, gave the following numbers : 0*2325 grammes of the salt yielded 0*4427 grammes of COj, 0*0687 grammes HjO, and 0*0595 grammes Ag.


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