Physical Chemistry in the Service of the Sciences 18

Cover Physical Chemistry in the Service of the Sciences 18
Physical Chemistry in the Service of the Sciences 18
J H Vant Jacobus Henricus Vant Hoff
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Thus, in dealing with hydrochloric acid, we 40 Physical Chemistby can see that the dissolved body is not HCl, but a mixture of H and CI, that is to say, of positively charged hydrogen and negatively charged chlorine atoms. That these charges of electricity should so profoundly alter the behi^vior that neither the familiar properties of hydrogen nor those of chlorine are perceptible in the hydrochloric acid solution, appears at first sight to be a serious objection. On closer consideration, howe...ver, we see that this conception may be accepted as a possibility, even if the difficulties have not been completely cleared up. Over against this ground of hesitation we are in a position to set a great number of facts which before the assumption of electrical dissociation were without explanation. Not only so, but this theory has enabled us to foretell chemical occurrences and to some extent account for them mathematically. It may be added that Baoult, who has devoted himself for more than twenty years to the study of dilute solutions, at first rejected this theory, but now fully concurs in the explanation offered by Arrhenius.

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