Practical Chemistry for Engineering Students

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is produced, of arsenic sulphide.
Equation — 2 AsClg + SH^S = AsgSg -t- 6HC1.
Exp. 4. Marsh's Test for Arsenic.
This is a very delicate test for arsenic, and is carried out as follows : — ■ Fit up a 4-oz. conical flask with thistle-funnel and right- angled tube, as shown in Fig. 51. The tube should be of hard glass, and should be drawn out at the end. Place in this flask a few pieces of zinc (arsenic free), and just cover them with distilled water. Then replace the cork, and pour a few drops of
... strong hydrochloric acid through the thistle-funnel.
Hydrogen gas will be evolved, and while the air is being expelled from the apparatus, dissolve a little arsenic oxide indilute hydro- chloric acid.
Now ascertain whether the hydrogen is air-free by collecting a test-tube of the gas by upward displacement, closing the mouth of the tube with the thumb, and bringing it mouth downwards to a flame.
If the gas burns quietly i,t may be lighted at the end of the Fig. 51.— {From Thorpe's ' tative Chemical Analysis") 104 CHEMISTKY FOR ENGINEERING STUDENTS tube, and continues burning with a blue flame.


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